Parts
Pharmacopoeias
express some concentrations in terms of the number of 'parts' of solute
dissolved in a stated number of 'parts' of solution.
Molarity : Moles of solute
per liter of solution.
[Example:
Molecular weight of NaOH is “40” (Na=23; O=16; H=1). When the unit of this
number is expressed as “gram” and when this 40 gm of NaOH is dissolved in 1
liter solution this is called “1 molar NaOH Solution”
Molality : Moles of solute
per kilogram of solvent.
[Example:
Molecular weight of NaOH is “40” (Na=23; O=16; H=1). When the unit of this
number is expressed as “gram” and when this 40 gm of NaOH is dissolved in 1 kilogram
of solvent this is called “1 molal NaOH Solution”
Normality : Equivalent
weight of solute per liter of solution.
[Example:
Molecular weight H2SO4 is “98” (and equivalent weight of H2SO4
is “46”. When the unit of this number is expressed as “gram” and when
this 46 gm of H2SO4 is dissolved in 1 liter solution this
is called “1 normal H2SO4 Solution”
Moles : When the
molecular weight of a compound expressed as mass and unit is “gram”, then this
amount is called as mole of that compound.
Mole fraction
This is often
used in theoretical considerations and is defined as the number of moles of
solute divided by the total number of moles of solute and solvent, i.e.:
n1
mole fraction of
solute ( x1 ) = -----------
n1
+ n2
where n\ and
n2
are
the numbers of moles of solute and solvent, respectively.
Mill/equivalents and normal solutions
The concentrations
of solutes in body fluids and in solutions
used as replacements for those fluids are usually expressed in terms of the
number of millimoles (1 millimole = one thousandth of a mole) in a litre of
solution. In the case of electrolytes, however, these concentrations may still
be expressed in terms of milliequivalents per litre. A milliequivalent (mEq) of
an ion is, in fact, one thousandth of the gram equivalent of the ion, which is
in turn the ionic weight expressed in grams divided by the valency of the ion.
Alternatively,
ionic weight in mg
1mEq =
----------------------------
valency
Percent:
One part per hundred is
generally represented by the percent (%) symbol and denotes one part per 100
parts, one part in 102
ppm:
One part per moillion (ppm)
denotes one part per 1,000,000 parts, one part in 106; One ppm is
equivalent to 1 milligram of something per liter of water (mg/l) or 1 milligram
of something per kilogram solid (mg/kg) (1/1,000,000)
ppb:
One part per billion (ppb) denotes one part per
1,000,000,000 parts, one part in 109, One ppb represents one microgram
of something per liter of water (ug/l), or one microgram of something per
kilogram of solid (ug/kg). (1/1,000,000,000)
ppt:
One part pertrillion (ppt)
denotes one part per 1,000,000,000,000 parts, one part in 1012
(1/1,000,000,000,000).
ppq:
One part per quadrillion (ppq) denotes one part per
1,000,000,000,000,000 parts, one part in 1015 (1/1,000,000,000,000,000).
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